Issue 98, 2015
From the journal:

Chemical Communications

l-Aspartate links for stable sodium metal–organic frameworks†

Peter Siman,a   Christopher A. Trickett,a   Hiroyasu Furukawaab  and  Omar M. Yaghi*ab  

* Corresponding authors

a Department of Chemistry, University of California – Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory, and Kavli Energy NanoSciences Institute at Berkeley, Berkeley, California 94720, USA
E-mail: yaghi@berkeley.edu

b King Fahd University of Petroleum and Minerals, Dhahran 34464, Saudi Arabia

Abstract

Metal–organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.

Graphical abstract: l-Aspartate links for stable sodium metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C5CC07578E
Article type
Communication
Submitted
10 Sep 2015
Accepted
30 Sep 2015
First published
30 Sep 2015

Chem. Commun., 2015,51, 17463-17466

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L-Aspartate links for stable sodium metal–organic frameworks

P. Siman, C. A. Trickett, H. Furukawa and O. M. Yaghi, Chem. Commun., 2015, 51, 17463 DOI: 10.1039/C5CC07578E

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