Issue 92, 2015
From the journal:

Chemical Communications

A metal-mediated boron-centred isomerisation reaction via C–H activation†

Holger Braunschweig,*a   J. Oscar C. Jimenez-Halla,b   Krzysztof Radackia  and  Rong Shanga  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany
E-mail: H.Braunschweig@uni-wuerzburg.de

b Department of Chemistry, Division of Natural and Exact Sciences, University of Guanajuato, Campus Gto, Noria Alta s/n, 36050 Guanajuato, Mexico
E-mail: jjimenez@ugto.mx

Abstract

A heterocyclic manganese complex (4) derived from a carbonyl–borylene coupling reaction undergoes isomerisation, during which the former borylene moiety migrates to the cyclopentadienyl ligand and inserts into a C–H bond. This reaction and a computational study of its mechanism are discussed.

Graphical abstract: A metal-mediated boron-centred isomerisation reaction via C–H activation

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Article information

DOI
https://doi.org/10.1039/C5CC07681A
Article type
Communication
Submitted
15 Sep 2015
Accepted
22 Sep 2015
First published
30 Sep 2015

Chem. Commun., 2015,51, 16569-16572

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A metal-mediated boron-centred isomerisation reaction via C–H activation

H. Braunschweig, J. O. C. Jimenez-Halla, K. Radacki and R. Shang, Chem. Commun., 2015, 51, 16569 DOI: 10.1039/C5CC07681A

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