Issue 19, 2015
From the journal:

Dalton Transactions

Geometrically unprecedented 3-, 5- and 7-membered Hg(ii)–Cu(i) and Hg(ii)–Ag(i) thiolate clusters: precursors to intermetallics†

Geetika Gupta,a   Jyotsna Chaturvedia  and  Subrato Bhattacharya*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi 221005, India
E-mail: s_bhatt@bhu.ac.in

Abstract

The syntheses of three polynuclear heterobimetallic complexes through the use of a homoleptic mercuric thiolate anion as a template for the assembly of coinage metal are presented. The complexes, [(PPh3)3Ag3(μ-SPh)7Hg2] (1), [Hg(μ-SPh)4{Cu(PPh3)2}2] (2) and [(dppe)2Cu5(μ-SPh)7Hg2(SPh)2] (3) were utilized as precursors for the fabrication of Hg–Ag and Hg–Cu intermetallics.

Graphical abstract: Geometrically unprecedented 3-, 5- and 7-membered Hg(ii)–Cu(i) and Hg(ii)–Ag(i) thiolate clusters: precursors to intermetallics

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Article information

DOI
https://doi.org/10.1039/C4DT03500C
Article type
Paper
Submitted
14 Nov 2014
Accepted
31 Mar 2015
First published
31 Mar 2015

Dalton Trans., 2015,44, 8932-8937

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Geometrically unprecedented 3-, 5- and 7-membered Hg(II)–Cu(I) and Hg(II)–Ag(I) thiolate clusters: precursors to intermetallics

G. Gupta, J. Chaturvedi and S. Bhattacharya, Dalton Trans., 2015, 44, 8932 DOI: 10.1039/C4DT03500C

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