Alkali metal-mediated dehydrocoupling of Me2NH·BH3

Peter Bellham; Michael S. Hill; Gabriele Kociok-Köhn

doi:10.1039/C5DT00178A

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Alkali metal-mediated dehydrocoupling of Me₂NH·BH₃†

Peter Bellham,^a Michael S. Hill*^a and Gabriele Kociok-Köhn^a

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^a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: msh27@bath.ac.uk

Abstract

Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me₂NH·BH₃via the formation of intermediates containing [H₃BNMe₂BH₂Me₂N]⁻ anions.

This article is part of the themed collection: Earth Abundant Element Compounds in Homogeneous Catalysis

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Article information

DOI: https://doi.org/10.1039/C5DT00178A
Article type: Communication
Submitted: 14 Jan 2015
Accepted: 09 Mar 2015
First published: 13 Mar 2015

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Dalton Trans., 2015,44, 12078-12081

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Alkali metal-mediated dehydrocoupling of Me₂NH·BH₃

P. Bellham, M. S. Hill and G. Kociok-Köhn, Dalton Trans., 2015, 44, 12078 DOI: 10.1039/C5DT00178A

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Dalton Transactions