Issue 12, 2015
From the journal:

Dalton Transactions

Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation†

Yasuhiro Arikawa,*a   Takuo Nakamura,a   Shinji Ogushi,a   Kazushige Eguchia  and  Keisuke Umakoshia  

* Corresponding authors

a Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University, Bunkyo-machi 1-14, Nagasaki 852-8521, Japan
E-mail: arikawa@nagasaki-u.ac.jp
Tel: +81 95-819-2673

Abstract

A methylcarbonato ruthenium complex was prepared by capture of CO2 from air using the (CNC)(bpy)Ru scaffold. The methylcarbonato complex was relatively inert to decarboxylation. Treatments with methylating reagents released dimethylcarbonate.

Graphical abstract: Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation

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Article information

DOI
https://doi.org/10.1039/C5DT00476D
Article type
Communication
Submitted
02 Feb 2015
Accepted
12 Feb 2015
First published
12 Feb 2015

Dalton Trans., 2015,44, 5303-5305

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Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation

Y. Arikawa, T. Nakamura, S. Ogushi, K. Eguchi and K. Umakoshi, Dalton Trans., 2015, 44, 5303 DOI: 10.1039/C5DT00476D

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