Issue 19, 2015
From the journal:

Dalton Transactions

Synthesis of a new type of alkene metal complex using face-capping thione-alkene ligands†

Long Zhang,a   Tao Yan,a   Ying-Feng Han,*a   F. Ekkehardt Hahnab  and  Guo-Xin Jin*a  

* Corresponding authors

a Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433 Shanghai, People's Republic of China
E-mail: yfhan1980@fudan.edu.cn, gxjin@fudan.edu.cn

b Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstraße 30, D-48149 Münster, Germany

Abstract

A series of complexes of novel chelating thione-alkene S(η2-C[double bond, length as m-dash]C)S tridentate ligands bound to late transition metals (Ir, Rh, Pd) were isolated and characterised. Counter-anions play an important role in the binding of the alkene moiety to the metals. Different solvents were observed to affect the stability of the rhodium complexes.

Graphical abstract: Synthesis of a new type of alkene metal complex using face-capping thione-alkene ligands

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5DT01311A
Article type
Communication
Submitted
06 Apr 2015
Accepted
15 Apr 2015
First published
15 Apr 2015

Dalton Trans., 2015,44, 8797-8800

Author version available

Download author version (PDF)

Permissions

Request permissions

Synthesis of a new type of alkene metal complex using face-capping thione-alkene ligands

L. Zhang, T. Yan, Y. Han, F. E. Hahn and G. Jin, Dalton Trans., 2015, 44, 8797 DOI: 10.1039/C5DT01311A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements