Issue 46, 2015
From the journal:

Dalton Transactions

Dinuclear lanthanide(iii)/zinc(ii) complexes with methyl 2-pyridyl ketone oxime†

Nikolaos C. Anastasiadis,ab   Christina D. Polyzou,ab   George E. Kostakis, ORCID logo ac   Vlasoula Bekiari,d   Yanhua Lan,e   Spyros P. Perlepes,b   Konstantis F. Konidaris ORCID logo *a  and  Annie K. Powell*ae  

* Corresponding authors

a Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
E-mail: konstantis.konidaris@gmail.com

b Department of Chemistry, University of Patras, GR-265 04 Patras, Greece

c Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK

d Department of Aquaculture, Technological Educational Institute of Western Greece, GR-30200 Messolonghi, Greece

e Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany
E-mail: annie.powell@kit.edu

Abstract

The first use of methyl 2-pyridyl ketone oxime (mpkoH) in zinc(II)/lanthanide(III) chemistry leads to the [ZnLn(mpko)3(mpkoH)3](ClO4)2 and [ZnLn(NO3)2(mpko)3(mpkoH)] families of dinuclear ZnIILnIII complexes displaying blue-green, ligand-based photoluminescence; the ZnIIDyIII compound shows field-induced relaxation of magnetization.

Graphical abstract: Dinuclear lanthanide(iii)/zinc(ii) complexes with methyl 2-pyridyl ketone oxime

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Article information

DOI
https://doi.org/10.1039/C5DT03663A
Article type
Communication
Submitted
18 Sep 2015
Accepted
07 Oct 2015
First published
14 Oct 2015
This article is Open Access
Creative Commons BY license

Dalton Trans., 2015,44, 19791-19795

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Dinuclear lanthanide(III)/zinc(II) complexes with methyl 2-pyridyl ketone oxime

N. C. Anastasiadis, C. D. Polyzou, G. E. Kostakis, V. Bekiari, Y. Lan, S. P. Perlepes, K. F. Konidaris and A. K. Powell, Dalton Trans., 2015, 44, 19791 DOI: 10.1039/C5DT03663A

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