A metal-dependent and complementary catalytic method to synthesize the cyclohexadienes has been developed. When gold or indium salts were used as catalysts, 1,3-cyclohexadiene (1,3-CHD) could be obtained; when Cu(OTf)2 was used as the catalyst, however, another isomer 2,4-cyclohexadiene (2,4-CHD) was furnished instead.
S. Zhu, X. Huang, T. Zhao, T. Ma and H. Jiang, Org. Biomol. Chem., 2015, 13, 1225 DOI: 10.1039/C4OB01922A
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