We report herein a highly exo-selective intramolecular Diels–Alder reaction of alkenyl boronates which employs an N–B dative bond-involved bicyclic rigid tether. Complex C(sp3)-rich polycyclic molecules containing up to 8 stereocenters can be readily formed via an operationally simple two-step procedure.
![Graphical abstract: N–B dative bond-induced [3.3.0] bicyclic boronate-tethered exo-selective intramolecular Diels–Alder reaction](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C5OB00917K&imageInfo.ImageIdentifier.Year=2015)
C. Feng, H. Wang, L. Xu and P. Li, Org. Biomol. Chem., 2015, 13, 7136 DOI: 10.1039/C5OB00917K
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