Treatment of (ortho-trimethysilyl)aryl phenylsulfonates with a soluble fluoride source initiates a Truce-Smiles rearrangement leading to the formation of functionalized bi-aryls. This new carbon–carbon bond-forming reaction proceeds without recourse to transition metal catalysis, under mild reaction conditions and with good functional group compatibility.
O. K. Rasheed, I. R. Hardcastle, J. Raftery and P. Quayle, Org. Biomol. Chem., 2015, 13, 8048 DOI: 10.1039/C5OB01239B
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