Issue 10, 2015
From the journal:

Inorganic Chemistry Frontiers

Cyclometallation of the NNN pincer ligand in complexes of platinum†

Jessica C. DeMott,a   John R. Dekarske,‡a   Billy J. McCullocha  and  Oleg V. Ozerov*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, TX 77842, USA
E-mail: ozerov@chem.tamu.edu

Abstract

Platinum complexes of the diimino/carbazolyl NNN pincer ligand have been prepared and characterized. Cyclometallation of the mesityl substituent was observed to occur unexpectedly easily in (NNN)PtOTf, which also catalyzed cyclometallation in (NNN)PtMe.

Graphical abstract: Cyclometallation of the NNN pincer ligand in complexes of platinum

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Article information

DOI
https://doi.org/10.1039/C5QI00102A
Article type
Research Article
Submitted
17 Jun 2015
Accepted
28 Aug 2015
First published
28 Aug 2015

Inorg. Chem. Front., 2015,2, 912-916

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Cyclometallation of the NNN pincer ligand in complexes of platinum

J. C. DeMott, J. R. Dekarske, B. J. McCulloch and O. V. Ozerov, Inorg. Chem. Front., 2015, 2, 912 DOI: 10.1039/C5QI00102A

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