A triphenylene-based conjugated microporous polymer: construction, gas adsorption, and fluorescence detection properties†
Abstract
A triphenylene-based conjugated microporous polymer (TP-CMP) has been synthesized and shows high surface area (SBET = 1104 m2 g−1) and remarkable uptakes of H2 (7.08 mmol g−1 at 77 K and 900 mmHg) and CO2 (3.37 mmol g−1 at 273 K and 900 mmHg). In addition, it could be utilized to detect nitrobenzene selectively via fluorescence quenching.