Issue 26, 2015

Palladium nanoparticles supported on 1,3-dicyclohexylguanidine functionalized mesoporous silica SBA-15 as highly active and reusable catalyst for the Suzuki–Miyaura cross-coupling reaction

Abstract

This paper describes a simple procedure for the synthesis and application of SBA-15/1,3-DCG/Pd as a novel nano catalyst in Suzuki–Miyaura cross-coupling reactions under atmospheric conditions in aqueous media. The SBA-15/1,3-DCG/Pd is air and moisture stable and readily prepared and the results indicated that palladium nanoparticles (Pd NPs) with an average size of 10 nm were uniformly dispersed onto the inorganic support. Aryl halides, coupled with phenyl boronic acid, smoothly afford the corresponding cross-coupling products with good to excellent yields (83–99%). It was found that the catalytic system showed excellent activity for the Suzuki–Miyaura cross-coupling reaction of less reactive aryl chlorides with phenyl boronic acid. The reaction conditions have been evaluated considering the effect of various parameters such as reaction time, temperature, amount of catalyst, amount of base and its nature and solvent. The catalyst is completely recoverable in a facile manner from the reaction mixture and the efficiency of the nano catalyst remains unaltered even after five cycles.

Graphical abstract: Palladium nanoparticles supported on 1,3-dicyclohexylguanidine functionalized mesoporous silica SBA-15 as highly active and reusable catalyst for the Suzuki–Miyaura cross-coupling reaction

Associated articles

Article information

Article type
Paper
Submitted
16 Nov 2014
Accepted
11 Feb 2015
First published
19 Feb 2015

RSC Adv., 2015,5, 20098-20107

Palladium nanoparticles supported on 1,3-dicyclohexylguanidine functionalized mesoporous silica SBA-15 as highly active and reusable catalyst for the Suzuki–Miyaura cross-coupling reaction

H. Veisi, A. Amini Manesh, N. Eivazi and A. R. Faraji, RSC Adv., 2015, 5, 20098 DOI: 10.1039/C4RA14668A

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