Issue 14, 2015

Microwave-promoted solventless Mizoroki–Heck reactions catalysed by Pd nanoparticles supported on laponite clay

Abstract

A new family of solid catalysts has been prepared by supporting palladium nanoparticles on a synthetic clay (laponite) using a straightforward and robust procedure. These solids have been used as catalysts in a Mizoroki–Heck reaction, in solventless conditions, activated by microwave radiation. Complete conversions and high product yields can be obtained in a few minutes, and the catalyst can be efficiently recovered by extracting reaction products in essentially pure form. In the best cases, catalysts can be used up to thirteen times with good results.

Graphical abstract: Microwave-promoted solventless Mizoroki–Heck reactions catalysed by Pd nanoparticles supported on laponite clay

Supplementary files

Article information

Article type
Paper
Submitted
28 Nov 2014
Accepted
06 Jan 2015
First published
06 Jan 2015

RSC Adv., 2015,5, 10102-10109

Author version available

Microwave-promoted solventless Mizoroki–Heck reactions catalysed by Pd nanoparticles supported on laponite clay

A. V. Martínez, F. Invernizzi, A. Leal-Duaso, J. A. Mayoral and J. I. García, RSC Adv., 2015, 5, 10102 DOI: 10.1039/C4RA15418E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements