Issue 7, 2015
From the journal:

RSC Advances

Atom-economical chemoselective synthesis of furocoumarins via cascade palladium catalyzed oxidative alkoxylation of 4-oxohydrocoumarins and alkenes†

Xian-chun Tan,‡a   Hai-yuan Zhao,‡a   Ying-ming Pan,*a   Na Wu,a   Heng-shan Wanga  and  Zhen-feng Chen*a  

* Corresponding authors

a Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and Pharmaceutical Sciences of Guangxi Normal University, Guilin 541004, People's Republic of China
E-mail: panym2013@hotmail.com, chenzfubc@yahoo.com
Fax: +86-773-5803930
Tel: +86-773-5846279

Abstract

A novel and efficient procedure for the synthesis of furo[3,2-c]coumarins from readily available 4-oxohydrocoumarins and alkenes in the presence of a catalytic amount of Pd(CF3COO)2 has been developed. Atom-economical characteristics and mild conditions of this method are in accord with the concept of modern green chemistry.

Graphical abstract: Atom-economical chemoselective synthesis of furocoumarins via cascade palladium catalyzed oxidative alkoxylation of 4-oxohydrocoumarins and alkenes

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Article information

DOI
https://doi.org/10.1039/C4RA15732J
Article type
Communication
Submitted
25 Oct 2014
Accepted
10 Dec 2014
First published
11 Dec 2014

RSC Adv., 2015,5, 4972-4975

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Atom-economical chemoselective synthesis of furocoumarins via cascade palladium catalyzed oxidative alkoxylation of 4-oxohydrocoumarins and alkenes

X. Tan, H. Zhao, Y. Pan, N. Wu, H. Wang and Z. Chen, RSC Adv., 2015, 5, 4972 DOI: 10.1039/C4RA15732J

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