Issue 31, 2015
From the journal:

RSC Advances

Zeolitic imidazolate frameworks as heterogeneous catalysts for a one-pot P–C bond formation reaction via Knoevenagel condensation and phospha-Michael addition†

Yu Horiuchi,*a   Takashi Toyao,a   Mika Fujiwaki,a   Satoru Dohshi,b   Tae-Ho Kimc  and  Masaya Matsuoka*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1, Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan
E-mail: horiuchi@chem.osakafu-u.ac.jp, matsumac@chem.osakafu-u.ac.jp
Fax: +81-72-254-9910
Tel: +81-72-254-9282

b Technology Research Institute of Osaka Prefecture, 1-18-13, Kishibe-naka, Suita, Japan

c Division of Mechanics and ICT Convergence Engineering, Sun Moon University, Republic of Korea

Abstract

A sequential one-pot reaction to produce organophosphorus compounds via Knoevenagel condensation and phospha-Michael addition has been realised by utilising ZIF-8 as a heterogeneous catalyst. The combination of 2-methylimidazolate anions and Zn2+ cations in ZIF-8 is revealed to be effective for the efficient promotion of the one-pot reaction.

Graphical abstract: Zeolitic imidazolate frameworks as heterogeneous catalysts for a one-pot P–C bond formation reaction via Knoevenagel condensation and phospha-Michael addition

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Article information

DOI
https://doi.org/10.1039/C5RA02410B
Article type
Communication
Submitted
23 Dec 2014
Accepted
26 Feb 2015
First published
26 Feb 2015

RSC Adv., 2015,5, 24687-24690

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Zeolitic imidazolate frameworks as heterogeneous catalysts for a one-pot P–C bond formation reaction via Knoevenagel condensation and phospha-Michael addition

Y. Horiuchi, T. Toyao, M. Fujiwaki, S. Dohshi, T. Kim and M. Matsuoka, RSC Adv., 2015, 5, 24687 DOI: 10.1039/C5RA02410B

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