Issue 54, 2015

Influence of earth-abundant bimetallic (Fe–Ni) nanoparticle-embedded CNFs as a low-cost counter electrode material for dye-sensitized solar cells

Abstract

Earth-abundant bimetallic (Fe–Ni) nanoparticle-embedded carbon nanofibers (CNFs) have been prepared by electrospinning technique and used as counter electrode (CE) material for dye-sensitized solar cells (DSSC). The structural and morphological properties were explored by X-ray diffraction (XRD), Raman spectroscopy, field-emission scanning microscope (FE-SEM) and transmission electron microscope (TEM) studies. The results of cyclic voltammetry (CV), electrochemical impedance and Tafel polarization studies revealed that (Fe–Ni)-CNFs demonstrated superior electrocatalytic activity, electrochemical stability, low charge transfer resistance (Rct) and high exchange current density for the reduction of triiodide (I3). Furthermore, it was observed that DSSC fabricated using (Fe–Ni)-CNFs as counter electrode had achieved power conversion efficiency (PCE) that is almost comparable to the same fabricated using std. Pt. This is due to the prepared CNFs' large surface area and randomly oriented, interconnected porous morphology with graphitized structure, which enhanced the contact with a large quantity of ionic liquid electrolyte, leading to a faster redox kinetics of I3/I. This study revealed that (Fe–Ni)-CNFs could be used as a low-cost and efficient counter electrode material for DSSCs.

Graphical abstract: Influence of earth-abundant bimetallic (Fe–Ni) nanoparticle-embedded CNFs as a low-cost counter electrode material for dye-sensitized solar cells

Article information

Article type
Paper
Submitted
20 Mar 2015
Accepted
28 Apr 2015
First published
28 Apr 2015

RSC Adv., 2015,5, 43611-43619

Author version available

Influence of earth-abundant bimetallic (Fe–Ni) nanoparticle-embedded CNFs as a low-cost counter electrode material for dye-sensitized solar cells

K. Saranya, A. Subramania and N. Sivasankar, RSC Adv., 2015, 5, 43611 DOI: 10.1039/C5RA04963F

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