Issue 46, 2015
From the journal:

RSC Advances

A radiation sensitive hybrid polymer based on an Mn-Anderson polyoxometalate cluster and a UV active organic monomer: synergistic effects lead to improved photocurrent in a photoresponse device†

Vishwanath Kalyani,a   V. S. V. Satyanarayana,a   Abdus Salam Sarkar,a   Ashwani Kumar,a   Suman K. Pal,a   Subrata Ghosh,a   Kenneth E. Gonsalves*a  and  Chullikkattil P. Pradeep*a  

* Corresponding authors

a School of Basic Sciences, Indian Institute of Technology Mandi, Mandi 175001, Himachal Pradesh, India
E-mail: pradeep@iitmandi.ac.in, kenneth@iitmandi.ac.in
Fax: +91 1905 267 009
Tel: +91 1905 267 045

Abstract

A new radiation sensitive polyoxometalate/polymer hybrid, POM–MAPDST, has been synthesized from an Mn-Anderson cluster based hybrid and a UV active organic monomer and tested for its photo-response properties by fabricating an ITO/POM–MAPDST/Al device. This device showed improved I–V characteristics under illumination possibly due to the synergistic interactions between the polyoxometalate cluster and the organic components of the hybrid polymer.

Graphical abstract: A radiation sensitive hybrid polymer based on an Mn-Anderson polyoxometalate cluster and a UV active organic monomer: synergistic effects lead to improved photocurrent in a photoresponse device

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Article information

DOI
https://doi.org/10.1039/C5RA05550D
Article type
Communication
Submitted
29 Mar 2015
Accepted
17 Apr 2015
First published
17 Apr 2015

RSC Adv., 2015,5, 36727-36731

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A radiation sensitive hybrid polymer based on an Mn-Anderson polyoxometalate cluster and a UV active organic monomer: synergistic effects lead to improved photocurrent in a photoresponse device

V. Kalyani, V. S. V. Satyanarayana, A. S. Sarkar, A. Kumar, S. K. Pal, S. Ghosh, K. E. Gonsalves and C. P. Pradeep, RSC Adv., 2015, 5, 36727 DOI: 10.1039/C5RA05550D

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