Issue 43, 2015
From the journal:

RSC Advances

Bis(imidazolium) salts derived from amino acids as receptors and transport agents for chloride anions†

Laura González-Mendoza,a   Belén Altava,*a   M. Isabel Burguete,a   Jorge Escorihuela,b   Elsa Hernando,c   Santiago V. Luis,*a   Roberto Quesadac  and  Cristian Vicentd  

* Corresponding authors

a Departamento de Química Inorgánica y Orgánica, Universitat Jaume I, Av. Sos Baynat, s/n, E-12071 Castellón, Spain
E-mail: luiss@uji.es, altava@uji.es
Fax: +34 964728214

b Wageningen UR, Laboratory of Organic Chemistry, Dreijenplein 8, 6703 HB Wageningen, The Netherlands

c Departamento de Química, Facultad de Ciencias, Universidad de Burgos, 09001 Burgos, Spain

d Serveis Centrals d'Instrumentació Científica, Universitat Jaume I, Avda. Sos Baynat, s/n, 12071 Castellón, Spain

Abstract

The binding properties of bis(imidazolium) hosts 1a–c derived from amino acids towards different anions have been studied by 1H NMR titration experiments in 95 : 05 CD3CN : H2O at 303 K, ESI-MS and theoretical calculations. Among this family, the salt 1c showed a strong and high selectivity for chloride anions. Transmembrane chloride transport activity has also been studied for the three bis(imidazolium) based transporters in POPC liposome models, and compound 1a was identified as an active chloride/nitrate exchanger.

Graphical abstract: Bis(imidazolium) salts derived from amino acids as receptors and transport agents for chloride anions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5RA05880E
Article type
Paper
Submitted
02 Apr 2015
Accepted
08 Apr 2015
First published
08 Apr 2015
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2015,5, 34415-34423

Author version available

Download author version (PDF)

Permissions

Request permissions

Bis(imidazolium) salts derived from amino acids as receptors and transport agents for chloride anions

L. González-Mendoza, B. Altava, M. I. Burguete, J. Escorihuela, E. Hernando, S. V. Luis, R. Quesada and C. Vicent, RSC Adv., 2015, 5, 34415 DOI: 10.1039/C5RA05880E

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements