Issue 50, 2015

Hierarchical ZnO@MnO2@PPy ternary core–shell nanorod arrays: an efficient integration of active materials for energy storage

Abstract

In this paper, ZnO@MnO2@PPy ternary core–shell nanorod arrays (NRAs) were fabricated through the layer-by-layer process. In this process, the incorporation of polypyrrole, a highly conductive material, on the surface of a binary ZnO@MnO2 core–shell structured composite is adopted to optimize the charge transfer process to further improve the electrochemical performance. Because of enhanced electron transfer capability, charge transfer resistances of the ZnO@MnO2@PPy ternary core–shell nanorod arrays are reduced and the electrochemical performances are improved. The electrochemistry tests show that these self-supported electrodes are able to deliver ultrahigh specific capacitance (1281 F g−1 at a current density of 2.5 A g−1), together with a considerable areal capacitance (1.793 F cm−2 at a current density of 3.5 mA cm−2). Furthermore, a capacitance retention of 90% after 5000 charge–discharge cycles at 5 A g−1 is obtained, indicating the excellent cycling stability of the ZnO@MnO2@PPy ternary core–shell electrode. The superior electrochemical capacity demonstrates the potential of ZnO@MnO2@PPy ternary core–shell NRAs to further improve the performance in supercapacitor electrodes.

Graphical abstract: Hierarchical ZnO@MnO2@PPy ternary core–shell nanorod arrays: an efficient integration of active materials for energy storage

Supplementary files

Article information

Article type
Paper
Submitted
15 Apr 2015
Accepted
23 Apr 2015
First published
23 Apr 2015

RSC Adv., 2015,5, 39864-39869

Hierarchical ZnO@MnO2@PPy ternary core–shell nanorod arrays: an efficient integration of active materials for energy storage

W. Ma, Q. Shi, H. Nan, Q. Hu, X. Zheng, B. Geng and X. Zhang, RSC Adv., 2015, 5, 39864 DOI: 10.1039/C5RA06765K

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