A simple and environment-friendly protocol for the palladium-catalyzed ligand-free Suzuki–Miyaura reaction of heteroaryl halides with N-methyliminodiacetic acid (MIDA) boronates is developed. The reaction is performed in water as the sole medium and allows the preparation of a variety of heterobiaryls in excellent yields.
C. Liu, X. Li, C. Liu, X. Wang and J. Qiu, RSC Adv., 2015, 5, 54312 DOI: 10.1039/C5RA10001A
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