Synergistic strategies for the preparation of highly efficient dye-sensitized solar cells on plastic substrates: combination of chemical and physical sintering

Abstract

Preparation of well-interconnected TiO₂ electrodes at low temperature is critical for the fabrication of highly efficient dye-sensitized solar cells (DSCs) on plastic substrates. Herein we explore a synergistic approach using a combination of chemical and physical sintering. We formulate a binder-free TiO₂ paste based on “nanoglue” as the chemical sintering agent, and use it to construct a photoelectrode on plastic by low-temperature physical compression to further improve the connectivity of TiO₂ films. We systematically investigated the factors affecting the photovoltaic performance and found the conditions to achieve electron diffusion lengths as long as 25 μm and charge collection efficiencies as high as 95%, as electrochemical impedance spectroscopy measurements indicate. We apply this approach to obtain a DSC deposited on plastic displaying 6.4% power conversion efficiency based on commercial P25 titania particles.