Ruthenium-catalyzed ortho-selective C–H arylation of acylarenes with halogenated aryl-boronates was promoted by the catalytic amount of bases and provided desired halogenated biaryls in excellent yields under 0.2–1 mol% ruthenium catalyst loading.
T. Yamamoto and T. Yamakawa, RSC Adv., 2015, 5, 105829 DOI: 10.1039/C5RA19810K
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