Issue 21, 2015

Exploring the potential of polymer battery cathodes with electrically conductive molecular backbone

Abstract

Organic redox materials have the potential to radically shift the battery technology landscape. Here, the chemical synthesis of poly(2,5-dihydroxyaniline) with intrinsic electrical conduction and a theoretical energy storage capacity of 443 mA h g−1 is detailed for the first time. The genuine intramolecular cross-hybridization of quinone redox and polyaniline conductor moieties leads to a subtle interplay between redox stability and the lithiation capacity with the underlying processes being discussed. Superior to the conventional electrode materials performances are expected upon further optimization of this novel class of organic redox materials with ion and electron conduction for energy storage.

Graphical abstract: Exploring the potential of polymer battery cathodes with electrically conductive molecular backbone

Supplementary files

Article information

Article type
Communication
Submitted
26 Feb 2015
Accepted
29 Apr 2015
First published
29 Apr 2015

J. Mater. Chem. A, 2015,3, 11189-11193

Author version available

Exploring the potential of polymer battery cathodes with electrically conductive molecular backbone

A. Vlad, K. Arnould, B. Ernould, L. Sieuw, J. Rolland and J. Gohy, J. Mater. Chem. A, 2015, 3, 11189 DOI: 10.1039/C5TA01500F

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