Nanoscale MIL-101 supported RhNi nanoparticles: an efficient catalyst for hydrogen generation from hydrous hydrazine

Pingping Zhao; Nan Cao; Wei Luo; Gongzhen Cheng

doi:10.1039/C5TA02201K

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Nanoscale MIL-101 supported RhNi nanoparticles: an efficient catalyst for hydrogen generation from hydrous hydrazine†

Pingping Zhao,^a Nan Cao,^a Wei Luo*^ab and Gongzhen Cheng^a

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* Corresponding authors

^a College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, P. R. China
E-mail: wluo@whu.edu.cn
Tel: +86 2768752366

^b Suzhou Institute of Wuhan University, Suzhou, Jiangsu, P. R. China

Abstract

Nanoscale MIL-101 has been controlled, synthesized by a seeding method, and further used as the support for immobilizing RhNi nanoparticles (NPs) as efficient catalysts toward hydrogen generation from hydrous hydrazine in alkaline solution. Compared with other commercial materials and bulk MIL-101, RhNi NPs supported on nanoscale MIL-101 exhibit the highest catalytic activity and 100% hydrogen selectivity.

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Article information

DOI: https://doi.org/10.1039/C5TA02201K
Article type: Paper
Submitted: 26 Mar 2015
Accepted: 06 May 2015
First published: 06 May 2015

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J. Mater. Chem. A, 2015,3, 12468-12475

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Nanoscale MIL-101 supported RhNi nanoparticles: an efficient catalyst for hydrogen generation from hydrous hydrazine

P. Zhao, N. Cao, W. Luo and G. Cheng, J. Mater. Chem. A, 2015, 3, 12468 DOI: 10.1039/C5TA02201K

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Journal of Materials Chemistry A

Nanoscale MIL-101 supported RhNi nanoparticles: an efficient catalyst for hydrogen generation from hydrous hydrazine†

Abstract

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Nanoscale MIL-101 supported RhNi nanoparticles: an efficient catalyst for hydrogen generation from hydrous hydrazine

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