Issue 1, 2015
From the journal:

Journal of Materials Chemistry B

Effects of fluorine on the structure of fluorohydroxyapatite: a study by XRD, solid-state NMR and Raman spectroscopy†

Jinshuai Chen,‡ab   Zhiwu Yu,‡c   Peizhi Zhu,*ab   Junfeng Wang,c   Zhehong Gan,d   Jie Wei,e   Yinghui Zhaof  and  Shicheng Wei*f  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu, P.R. China
E-mail: pzzhu@yzu.edu.cn

b Jiangsu Co-innovation Center for Prevention and Control of Important Animal Infectious Diseases and Zoonoses, Yangzhou, P.R. China

c High Magnetic Field Laboratory, Hefei Institutes of Physical Science, Chinese Academy of Sciences, 350 Shushanhu Road, Hefei 230031, Anhui Province, P.R. China

d Center of Interdisciplinary Magnetic Resonance, National High Magnetic Field Laboratory, Tallahassee, FL, USA

e Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, Shanghai, P.R. China

f Department of Oral and Maxillofacial Surgery, Laboratory of Interdisciplinary Studies, School and Hospital of Stomatology, Peking University, Beijing 100081, P.R. China
E-mail: sc-wei@pku.edu.cn

Abstract

For the first time we observed well-resolved Ca(I) and Ca(II) signal changes in fluorohydroxyapatites with different fluorine contents by solid state NMR. The experiment results show that fluorine ions perturb the chemical environment of Ca(II) ions and OH− ions more than phosphorus tetrahedra and Ca(I) ions.

Graphical abstract: Effects of fluorine on the structure of fluorohydroxyapatite: a study by XRD, solid-state NMR and Raman spectroscopy

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Article information

DOI
https://doi.org/10.1039/C4TB01561D
Article type
Communication
Submitted
21 Sep 2014
Accepted
04 Nov 2014
First published
05 Nov 2014

J. Mater. Chem. B, 2015,3, 34-38

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Effects of fluorine on the structure of fluorohydroxyapatite: a study by XRD, solid-state NMR and Raman spectroscopy

J. Chen, Z. Yu, P. Zhu, J. Wang, Z. Gan, J. Wei, Y. Zhao and S. Wei, J. Mater. Chem. B, 2015, 3, 34 DOI: 10.1039/C4TB01561D

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