Cobalester, a natural nontoxic vitamin B12 derivative, was found to catalyse unusual olefinic sp2 C–H alkylation with diazo reagents as a carbene source instead of the expected cyclopropanation.
M. Giedyk, K. Goliszewska, K. ó Proinsias and D. Gryko, Chem. Commun., 2016, 52, 1389 DOI: 10.1039/C5CC07363D
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