Issue 1, 2016

Reactivity differences of Sc3N@C2n (2n = 68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D5h-C80

Abstract

Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@Ih-C80 and Sc3N@D3h-C78 and a mixture of Sc3N@D5h-C80 and Sc3N@D3-C68. Taking advantage of their chemical reactivity differences, Sc3N@D5h-C80 was isolated from Sc3N@D3-C68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D5h-C80.

Graphical abstract: Reactivity differences of Sc3N@C2n (2n = 68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D5h-C80

Supplementary files

Article information

Article type
Communication
Submitted
04 Sep 2015
Accepted
29 Sep 2015
First published
29 Sep 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 64-67

Reactivity differences of Sc3N@C2n (2n = 68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D5h-C80

M. R. Cerón, M. Izquierdo, N. Alegret, J. A. Valdez, A. Rodríguez-Fortea, M. M. Olmstead, A. L. Balch, J. M. Poblet and L. Echegoyen, Chem. Commun., 2016, 52, 64 DOI: 10.1039/C5CC07416A

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