Issue 4, 2016
From the journal:

Chemical Communications

Connecting mononuclear dysprosium single-molecule magnets to form dinuclear complexes via in situ ligand oxidation†

Nathan J. Yutronkie,a   Irina A. Kühne,a   Ilia Korobkov,a   Jaclyn L. Brusso*a  and  Muralee Murugesu*a  

* Corresponding authors

a Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 Canada
E-mail: jbrusso@uottawa.ca, m.murugesu@uottawa.ca

Abstract

A Dy2 complex, exhibiting SMM behaviour, and its Y analogue were prepared via in situ oxidation of Py2TTA, a pincer type ligand, followed by dimerisation. This unique metal complexation and subsequent dimerization were followed by solution NMR studies.

Graphical abstract: Connecting mononuclear dysprosium single-molecule magnets to form dinuclear complexes via in situ ligand oxidation

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Article information

DOI
https://doi.org/10.1039/C5CC07629C
Article type
Communication
Submitted
11 Sep 2015
Accepted
30 Oct 2015
First published
05 Nov 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 677-680

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Connecting mononuclear dysprosium single-molecule magnets to form dinuclear complexes via in situ ligand oxidation

N. J. Yutronkie, I. A. Kühne, I. Korobkov, J. L. Brusso and M. Murugesu, Chem. Commun., 2016, 52, 677 DOI: 10.1039/C5CC07629C

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