Issue 7, 2016
From the journal:

Chemical Communications

Cooperative reaction chemistry derived from a borata-diene framework†

Jiangang Yu,a   Gerald Kehr,a   Constantin G. Daniliuc‡a  and  Gerhard Erker*a  

* Corresponding authors

a Organisch-Chemisches Institut der Universität Münster, Corrensstr. 40, 48149 Münster, Germany
E-mail: erker@uni-muenster.de

Abstract

The bifunctional frustrated BH−/B hydridoborate nucleophile/borane Lewis acid pair 6 is prepared starting from the borata-diene 3 by a sequence of sequential protonation/hydride attachment, followed by hydroboration with Piers' borane [HB(C6F5)2]. The trans-1,2-bifunctional system 6 reduced carbon monoxide eventually to the aldehyde product 10.

Graphical abstract: Cooperative reaction chemistry derived from a borata-diene framework

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Article information

DOI
https://doi.org/10.1039/C5CC07954C
Article type
Communication
Submitted
22 Sep 2015
Accepted
11 Nov 2015
First published
11 Nov 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 1393-1396

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Cooperative reaction chemistry derived from a borata-diene framework

J. Yu, G. Kehr, C. G. Daniliuc and G. Erker, Chem. Commun., 2016, 52, 1393 DOI: 10.1039/C5CC07954C

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