Porous metal–organic polyhedra (MOPs), constructed from heterometallic PdII–MII (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the PdII ions preferentially line the inner surface of the cage molecules. Careful activation produces co-ordinatively unsaturated 3d transition metal sites on the external MOP surfaces giving rise to H2 adsorption enthalpies in excess of −12 kJ mol−1.
J. M. Teo, C. J. Coghlan, J. D. Evans, E. Tsivion, M. Head-Gordon, C. J. Sumby and C. J. Doonan, Chem. Commun., 2016, 52, 276 DOI: 10.1039/C5CC08336B
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