Issue 11, 2016
From the journal:

Chemical Communications

Cyclic single-molecule magnets: from the odd-numbered heptanuclear to a dimer of heptanuclear dysprosium clusters†

Haiquan Tian,a   Song-Song Baoa  and  Li-Min Zheng*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
E-mail: lmzheng@nju.edu.cn

Abstract

A heptanuclear and a dimer of heptanuclear dysprosium clusters (Dy7 and Dy14) have been successfully synthesized by ingenious coalescence of the single and double pyrazinyl hydrazone as well as phosphonate ligands. The complexes feature the largest odd-numbered cyclic lanthanide clusters reported thus far. Both exhibit single molecule magnet behaviors at low temperature.

Graphical abstract: Cyclic single-molecule magnets: from the odd-numbered heptanuclear to a dimer of heptanuclear dysprosium clusters

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Article information

DOI
https://doi.org/10.1039/C5CC08740F
Article type
Communication
Submitted
21 Oct 2015
Accepted
11 Dec 2015
First published
11 Dec 2015

Chem. Commun., 2016,52, 2314-2317

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Cyclic single-molecule magnets: from the odd-numbered heptanuclear to a dimer of heptanuclear dysprosium clusters

H. Tian, S. Bao and L. Zheng, Chem. Commun., 2016, 52, 2314 DOI: 10.1039/C5CC08740F

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