Nine members of a family of nine-membered cyclic coordination clusters; Fe6Ln3 wheels (Ln = Gd to Lu and Y)

Irina A. Kühne; Valeriu Mereacre; Christopher E. Anson; Annie K. Powell

doi:10.1039/C5CC08887A

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Nine members of a family of nine-membered cyclic coordination clusters; Fe₆Ln₃ wheels (Ln = Gd to Lu and Y)†

Irina A. Kühne,^a Valeriu Mereacre,^a Christopher E. Anson^a and Annie K. Powell*^ab

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, KIT (Karlsruhe Institute of Technology), Engesserstr. 15, 76131 Karlsruhe, Germany
E-mail: annie.powell@kit.edu

^b Institut für Nanotechnologie, KIT (Karlsruhe Institute of Technology), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

We report a family of isostructural nonanuclear Fe^III–Ln^III cyclic coordination clusters [Fe^III₆Ln^III₃(μ-OMe)₉(vanox)₆(benz)₆]. (Ln = Tb (1), Dy (2), Ho (3), Er (4), Tm (5), Yb (6), Lu (7), Y (8) and Gd (9)), containing an odd number of metal ions. The planar cyclic coordination cluster cores are built up from three [Fe₂Ln] subunits.

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Article information

DOI: https://doi.org/10.1039/C5CC08887A
Article type: Communication
Submitted: 26 Oct 2015
Accepted: 13 Nov 2015
First published: 13 Nov 2015

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Chem. Commun., 2016,52, 1021-1024

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Nine members of a family of nine-membered cyclic coordination clusters; Fe₆Ln₃ wheels (Ln = Gd to Lu and Y)

I. A. Kühne, V. Mereacre, C. E. Anson and A. K. Powell, Chem. Commun., 2016, 52, 1021 DOI: 10.1039/C5CC08887A

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