Issue 26, 2016

Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

Abstract

An unstable diiron(II,II) complex possessing O2 binding ability at low temperature was encapsulated and stabilized in an ammonium-type ionic liquid layer polymerized on an electrode. The encapsulated complex revealed catalytic reactivity for four-electron reduction of O2 at an ambient temperature in aqueous solution.

Graphical abstract: Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

Supplementary files

Article information

Article type
Communication
Submitted
14 Dec 2015
Accepted
19 Feb 2016
First published
01 Mar 2016

Chem. Commun., 2016,52, 4780-4783

Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

T. Kitagawa, J. Nishino, T. Inomata, T. Ozawa, Y. Funahashi and H. Masuda, Chem. Commun., 2016, 52, 4780 DOI: 10.1039/C5CC10263D

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