Issue 16, 2016
From the journal:

Chemical Communications

Formation of a highly-ordered rigid multichromophoric 3D supramolecular network by combining ionic and coordination-driven self-assembly†

Antonia Kaloudi-Chantzea,a   Elisabeth Martinou,a   Kostas Seintis,b   Nikolaos Karakostas,a   Petros Giastas,c   Florian Pitterl,d   Herbert Oberacher,d   Mihalis Fakisb  and  George Pistolis*a  

* Corresponding authors

a NCSR “Demokritos” Institute of Nanoscience and Nanotechnology, 153 10 Athens, Greece
E-mail: g.pistolis@inn.demokritos.gr

b Department of Physics, University of Patras, 26500 Patras, Greece

c Hellenic Pasteur Inst, Dept Neurobiol, 11521 Athens, Greece

d Inst. of Legal Medicine and Core Facility Metabolomics, Medical Univ. of Innsbruck, Müllerstraße 44, 6020 Innsbruck, Austria

Abstract

We present here the self-assembly of a green-emitting metallosupramolecular rhomboid into a rigid, highly-ordered 3D multichromophoric network through the mediation of a tetra-anionic violet-blue molecular emitter. Control was obtained on the spatial topology, the electronic energy landscape and the fluorescence polarization of the interacting dipoles.

Graphical abstract: Formation of a highly-ordered rigid multichromophoric 3D supramolecular network by combining ionic and coordination-driven self-assembly

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Article information

DOI
https://doi.org/10.1039/C5CC10335E
Article type
Communication
Submitted
16 Dec 2015
Accepted
22 Jan 2016
First published
25 Jan 2016

Chem. Commun., 2016,52, 3388-3391

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Formation of a highly-ordered rigid multichromophoric 3D supramolecular network by combining ionic and coordination-driven self-assembly

A. Kaloudi-Chantzea, E. Martinou, K. Seintis, N. Karakostas, P. Giastas, F. Pitterl, H. Oberacher, M. Fakis and G. Pistolis, Chem. Commun., 2016, 52, 3388 DOI: 10.1039/C5CC10335E

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