Controlled electropolymerisation of a carbazole-functionalised iron porphyrin electrocatalyst for CO2 reduction

Xin-Ming Hu; Zakaria Salmi; Mie Lillethorup; Emil B. Pedersen; Marc Robert; Steen U. Pedersen; Troels Skrydstrup; Kim Daasbjerg

doi:10.1039/C6CC00982D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Controlled electropolymerisation of a carbazole-functionalised iron porphyrin electrocatalyst for CO₂ reduction†

Xin-Ming Hu,^ab Zakaria Salmi,^b Mie Lillethorup,^b Emil B. Pedersen,^b Marc Robert,^c Steen U. Pedersen,^ab Troels Skrydstrup^ab and Kim Daasbjerg*^ab

Author affiliations

* Corresponding authors

^a Carbon Dioxide Activation Center (CADIAC), Interdisciplinary Nanoscience Center (iNANO), Aarhus University, Gustav Wieds Vej 14, DK-8000 Aarhus C, Denmark

^b Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark
E-mail: kdaa@chem.au.dk

^c Laboratoire d'Electrochimie Moléculaire, Université Paris Diderot, Sorbonne Paris Cité, Unité Mixte de Recherche Université CNRS 7591, 75205 Paris Cedex 13, France

Abstract

Using a one-step electropolymerisation procedure, CO₂ absorbing microporous carbazole-functionalised films of iron porphyrins are prepared in a controlled manner. The electrocatalytic reduction of CO₂ for these films is investigated to elucidate their efficiency and the origin of their ultimate degradation.

Download options Please wait...

Supplementary files

Supplementary information PDF (1073K)

Article information

DOI: https://doi.org/10.1039/C6CC00982D
Article type: Communication
Submitted: 31 Jan 2016
Accepted: 30 Mar 2016
First published: 06 Apr 2016

Download Citation

Chem. Commun., 2016,52, 5864-5867

Permissions

Request permissions

Controlled electropolymerisation of a carbazole-functionalised iron porphyrin electrocatalyst for CO₂ reduction

X. Hu, Z. Salmi, M. Lillethorup, E. B. Pedersen, M. Robert, S. U. Pedersen, T. Skrydstrup and K. Daasbjerg, Chem. Commun., 2016, 52, 5864 DOI: 10.1039/C6CC00982D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications