Issue 36, 2016
From the journal:

Chemical Communications

Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): deprotonation-induced switching among nonaromatic, Möbius aromatic, and Hückel antiaromatic species†

Won-Young Cha,a   Takanori Soya,b   Takayuki Tanaka,b   Hirotaka Mori,b   Yongseok Hong,a   Sangsu Lee,a   Kyu Hyung Park,a   Atsuhiro Osuka*b  and  Dongho Kim*a  

* Corresponding authors

a Spectroscopy Laboratory for Functional π-Electronic Systems and Department of Chemistry, Yonsei University, Seoul 120-749, Korea
E-mail: dongho@yonsei.ac.kr

b Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto, Japan
E-mail: osuka@kuchem.kyoto-u.ac.jp

Abstract

Deprotonation of nonaromatic octakis-(pentafluorophenyl)-substituted [36]octaphyrin(1.1.1.1.1.1.1.1) with tetrabutylammonium fluoride (TBAF) afforded monoanionic twisted Möbius aromatic species and dianinonic square Hückel antiaromatic species, depending upon the amount of TBAF.

Graphical abstract: Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): deprotonation-induced switching among nonaromatic, Möbius aromatic, and Hückel antiaromatic species

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Article information

DOI
https://doi.org/10.1039/C6CC02051H
Article type
Communication
Submitted
08 Mar 2016
Accepted
27 Mar 2016
First published
29 Mar 2016

Chem. Commun., 2016,52, 6076-6078

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Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): deprotonation-induced switching among nonaromatic, Möbius aromatic, and Hückel antiaromatic species

W. Cha, T. Soya, T. Tanaka, H. Mori, Y. Hong, S. Lee, K. H. Park, A. Osuka and D. Kim, Chem. Commun., 2016, 52, 6076 DOI: 10.1039/C6CC02051H

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