Structures and magnetism of mono-palladium and mono-platinum doped Au25(PET)18 nanoclusters

Shubo Tian; Lingwen Liao; Jinyun Yuan; Chuanhao Yao; Jishi Chen; Jinlong Yang; Zhikun Wu

doi:10.1039/C6CC02698B

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Structures and magnetism of mono-palladium and mono-platinum doped Au₂₅(PET)₁₈ nanoclusters†

Shubo Tian,^a Lingwen Liao,^a Jinyun Yuan,^b Chuanhao Yao,^a Jishi Chen,^a Jinlong Yang^b and Zhikun Wu*^a

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* Corresponding authors

^a Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanostructures, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China
E-mail: zkwu@issp.ac.cn

^b Hefei National Laboratory for Physical Sciences at the Microscale and Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026, China

Abstract

Herein we report three important results of widespread interest, which are (1) the crystal structure of [Au₂₄Pt(PET)₁₈]⁰, (2) the crystal structure of [Au₂₄Pd(PET)₁₈]⁰ and (3) the main source of magnetism in [Au₂₅(PET)₁₈]⁰.

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Article information

DOI: https://doi.org/10.1039/C6CC02698B
Article type: Communication
Submitted: 31 Mar 2016
Accepted: 26 Jun 2016
First published: 27 Jun 2016

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Chem. Commun., 2016,52, 9873-9876

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Structures and magnetism of mono-palladium and mono-platinum doped Au₂₅(PET)₁₈ nanoclusters

S. Tian, L. Liao, J. Yuan, C. Yao, J. Chen, J. Yang and Z. Wu, Chem. Commun., 2016, 52, 9873 DOI: 10.1039/C6CC02698B

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Chemical Communications