Enantioselective sulfoxidation reaction is achieved for the first time by a DNA metalloenzyme assembled with the human telomeric G-quadruplex DNA and Cu(II)–4,4′-bimethyl-2,2′-bipyridine complex, and the mixed G-quadruplex architectures are responsible for the catalytic enantioselectivity and activity.
M. Cheng, Y. Li, J. Zhou, G. Jia, S. Lu, Y. Yang and C. Li, Chem. Commun., 2016, 52, 9644 DOI: 10.1039/C6CC03016E
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