Issue 69, 2016
From the journal:

Chemical Communications

Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper†

Yu Kamamoto,a   Yuya Nitta,a   Kazuyuki Kubo,a   Tsutomu Mizutaa  and  Shoko Kume*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Japan
E-mail: skume@hiroshima-u.ac.jp

Abstract

Two types of redox functionality were selected for covalent immobilization on a carbon electrode, using an electric potential as the sole stimulus. A redox-active copper catalyst transformed a terminal alkyne in two ways with and without an oxidation process, to form a triazole or butadiyne.

Graphical abstract: Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper

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Article information

DOI
https://doi.org/10.1039/C6CC03407A
Article type
Communication
Submitted
23 Apr 2016
Accepted
13 Jul 2016
First published
14 Jul 2016

Chem. Commun., 2016,52, 10486-10489

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Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper

Y. Kamamoto, Y. Nitta, K. Kubo, T. Mizuta and S. Kume, Chem. Commun., 2016, 52, 10486 DOI: 10.1039/C6CC03407A

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