Issue 70, 2016
From the journal:

Chemical Communications

Hexanuclear tin(ii) and mixed valence tin(ii,iv) oxide clusters within polyoxometalates†

Kosuke Suzuki,a   Takumi Hanaya,a   Rinta Sato,a   Takuo Minato,a   Kazuya Yamaguchia  and  Noritaka Mizuno*a  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: tmizuno@mail.ecc.u-tokyo.ac.jp
Fax: +81-3-5841-7220

Abstract

A hexanuclear mixed valence tin oxide cluster [Sn32+Sn34+O15]12− was successfully synthesized by the solution-state selective oxidation of a tin oxide cluster [Sn62+O12]12− within trivacant lacunary polyoxometalates, where lone pairs on the Sn2+ species acted as stereochemically active sites.

Graphical abstract: Hexanuclear tin(ii) and mixed valence tin(ii,iv) oxide clusters within polyoxometalates

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Article information

DOI
https://doi.org/10.1039/C6CC05284C
Article type
Communication
Submitted
24 Jun 2016
Accepted
02 Aug 2016
First published
03 Aug 2016

Chem. Commun., 2016,52, 10688-10691

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Hexanuclear tin(II) and mixed valence tin(II,IV) oxide clusters within polyoxometalates

K. Suzuki, T. Hanaya, R. Sato, T. Minato, K. Yamaguchi and N. Mizuno, Chem. Commun., 2016, 52, 10688 DOI: 10.1039/C6CC05284C

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