Continuous ZIF-67 polycrystalline membranes with effective propylene/propane separation performances were successfully fabricated through the incorporation of zinc ions into the ZIF-67 framework. The separation factor increases from 1.4 for the pure ZIF-67 membrane to 50.5 for the 90% zinc-substituted ZIF-67 membrane.
C. Wang, F. Yang, L. Sheng, J. Yu, K. Yao, L. Zhang and Y. Pan, Chem. Commun., 2016, 52, 12578 DOI: 10.1039/C6CC06457D
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