The Ritter-type amination of a tertiary C–H bond using iodic acid (HIO3) as an oxidant, in the presence of N-hydroxyphthalimide (NHPI) is reported. This operationally simple method is conducted under metal-free conditions, is scalable, and efficiently provides valuable α-tertiary amine derivatives.
K. Kiyokawa, K. Takemoto and S. Minakata, Chem. Commun., 2016, 52, 13082 DOI: 10.1039/C6CC07164C
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