Issue 97, 2016
From the journal:

Chemical Communications

Stepwise fabrication of donor/acceptor thin films with a charge-transfer molecular wire motif†

Yoshihiro Sekine,ab   Taiga Yokoyama,b   Norihisa Hoshino,c   Manabu Ishizaki,d   Katsuhiko Kanaizuka,d   Tomoyuki Akutagawa,c   Masa-aki Hagae  and  Hitoshi Miyasaka*ab  

* Corresponding authors

a Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
E-mail: miyasaka@imr.tohoku.ac.jp

b Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan

c Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

d Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa-machi, Yamagata, Japan

e Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan

Abstract

Novel thin films composed of a donor (D)/acceptor (A) charge-transfer chain compound were fabricated by a layer-by-layer technique using complexation of a paddlewheel-type diruthenium(II, II) complex with an N,N′-dicyanoquinonediimine derivative on an ITO substrate with a pyridine-substituted phosphonate anchor. The stepwise growth of an electron-transfer D+A−-chain thin film was confirmed.

Graphical abstract: Stepwise fabrication of donor/acceptor thin films with a charge-transfer molecular wire motif

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Article information

DOI
https://doi.org/10.1039/C6CC08310B
Article type
Communication
Submitted
15 Oct 2016
Accepted
08 Nov 2016
First published
08 Nov 2016

Chem. Commun., 2016,52, 13983-13986

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Stepwise fabrication of donor/acceptor thin films with a charge-transfer molecular wire motif

Y. Sekine, T. Yokoyama, N. Hoshino, M. Ishizaki, K. Kanaizuka, T. Akutagawa, M. Haga and H. Miyasaka, Chem. Commun., 2016, 52, 13983 DOI: 10.1039/C6CC08310B

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