Plasmonic properties of Ag nanoparticles embedded in GeO2–SiO2 matrix by atom beam sputtering

Abstract

Nanocomposite thin films containing Ag nanoparticles embedded in the GeO₂–SiO₂ matrix were synthesized by the atom beam co-sputtering technique. The structural, optical and plasmonic properties and the chemical composition of the nanocomposite thin films were studied by transmission electron microscopy (TEM) with energy dispersive X-ray spectroscopy (EDX), UV-visible absorption spectroscopy and X-ray photoelectron spectroscopy (XPS). UV-visible absorption studies on Ag–SiO₂ nanocomposites revealed the presence of a strong localized surface plasmon resonance (LSPR) peak characteristic of Ag nanoparticles at 413 nm, which showed a blue shift of 26 nm (413 to 387 nm) along with a significant broadening and drastic decrease in intensity with the incorporation of 16 at% of Ge into the SiO₂ matrix. TEM studies on Ag–GeO₂–SiO₂ nanocomposite thin films confirmed the presence of Ag nanoparticles with an average size of 3.8 nm in addition to their aggregates with an average size of 16.2 nm. Thermal annealing in air resulted in strong enhancement in the intensity of the LSPR peak, which showed a regular red shift of 51 nm (from 387 to 438 nm) with the increase in annealing temperature up to 500 °C. XPS studies showed that annealing in air resulted in oxidation of excess Ge atoms in the nanocomposite into GeO₂. Our work demonstrates the possibility of controllably tuning the LSPR of Ag nanoparticles embedded in the GeO₂–SiO₂ matrix by single-step thermal annealing, which is interesting for optical applications.