Mercury 5d-orbitals are involved in intramolecular π-interactions with carbon and sulfur nearest and next-nearest neighbors in mercury–aryl complexes. This unexpected character of the electron cloud of mercury was revealed by high energy-resolution XANES spectroscopy readily interpreted in terms of a final-state local (l,m)-projected density of states (DOS).
A. Lannes, A. Manceau, M. Rovezzi, P. Glatzel, Y. Joly and I. Gautier-Luneau, Dalton Trans., 2016, 45, 14035 DOI: 10.1039/C6DT02200F
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