Issue 6, 2016

Chemoselective cross-coupling reaction of sodium sulfinates with phenols under aqueous conditions

Abstract

An efficient procedure for the formation of C–S bonds via direct C–H functionalization has been developed under aqueous conditions. In this process, stable and readily available sodium sulfinates were used as the sulfur source to provide aryl sulfides and sulfones in good to excellent yields. A broad range of functional groups were well tolerated in this reaction system.

Graphical abstract: Chemoselective cross-coupling reaction of sodium sulfinates with phenols under aqueous conditions

Supplementary files

Article information

Article type
Paper
Submitted
24 Sep 2015
Accepted
26 Oct 2015
First published
26 Oct 2015

Green Chem., 2016,18, 1538-1546

Author version available

Chemoselective cross-coupling reaction of sodium sulfinates with phenols under aqueous conditions

F. Xiao, S. Chen, J. Tian, H. Huang, Y. Liu and G. Deng, Green Chem., 2016, 18, 1538 DOI: 10.1039/C5GC02292D

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