A series of new 7- and 4-azaindolo[1,2-f]phenanthridines were synthesized by a domino Pd(0)-catalyzed reaction, which involves three sequential steps: C–N coupling, hydroamination, and intramolecular C–H arylation. The products show promising fluorescence properties with high quantum yields (12–65%).
![Graphical abstract: Pd(0)-catalyzed domino C–N coupling/hydroamination/C–H arylation reactions: efficient synthesis and photophysical properties of azaindolo[1,2-f]phenanthridines](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C5OB02274F&imageInfo.ImageIdentifier.Year=2016)
T. N. Ngo, F. Janert, P. Ehlers, D. H. Hoang, T. T. Dang, A. Villinger, S. Lochbrunner and P. Langer, Org. Biomol. Chem., 2016, 14, 1293 DOI: 10.1039/C5OB02274F
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