A few rhodium complexes of N-heterocyclic carbenes were prepared through carbene transfer reactions and their structures were characterized by X-ray diffraction analysis. The rhodium complexes of NHCs are found to be efficient catalysts for vinylation of various triazoles via C–H activation. A number of double vinylated triazoles can be obtained in good yields.
S. Zhao, F. Wu, Y. Ma, W. Chen, M. Liu and H. Wu, Org. Biomol. Chem., 2016, 14, 2550 DOI: 10.1039/C5OB02397A
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