Palladium-catalyzed C–H alkylation reaction with alkylboronic acids has successfully been developed using a removable pyridyldiisopropylsilyl directing group. The amino acid played a crucial role as a ligand in the reaction. The alkylation protocol is also applicable to the coupling of C(sp3)–H bonds with alkylboronic acids.
Y. Zhang, H. Jiang, D. Chen and Y. Zhang, Org. Biomol. Chem., 2016, 14, 4585 DOI: 10.1039/C6OB00674D
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